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Firefighter Photo Andrea at Pixabay
20.09.2023

Intelligent Textiles as Protection against PAH Toxins

Fraunhofer IWS Supports Industry Partners in the Development of New Protective Suits for Firefighters.
Polycyclic aromatic hydrocarbon (PAHs) are considered harmful to health, especially as potential carcinogens. For example, the molecular compounds of carbon and hydrogen atoms can arise in house fires when mattresses, curtains, wooden beams, plastic, or other objects made of organic materials burn.

Polycyclic Aromatic Hydrocarbons PAH enter the body through the skin and are deposited in fatty tissue. Because the human defense systems are unaware of the ring-shaped carbon compounds, the body does not break down these pollutants – they accumulate and concentrate. This increases the risk of carcinoma over the years. According to “Deutsche Gesetzliche Unfallversicherung” (DGUV) studies, this risk is limited if protective clothing is worn correctly. However, minor carelessness can lead to problematic exposures when firefighters are on duty for decades.

Fraunhofer IWS Supports Industry Partners in the Development of New Protective Suits for Firefighters.
Polycyclic aromatic hydrocarbon (PAHs) are considered harmful to health, especially as potential carcinogens. For example, the molecular compounds of carbon and hydrogen atoms can arise in house fires when mattresses, curtains, wooden beams, plastic, or other objects made of organic materials burn.

Polycyclic Aromatic Hydrocarbons PAH enter the body through the skin and are deposited in fatty tissue. Because the human defense systems are unaware of the ring-shaped carbon compounds, the body does not break down these pollutants – they accumulate and concentrate. This increases the risk of carcinoma over the years. According to “Deutsche Gesetzliche Unfallversicherung” (DGUV) studies, this risk is limited if protective clothing is worn correctly. However, minor carelessness can lead to problematic exposures when firefighters are on duty for decades.

To better protect firefighters from these risks, the Fraunhofer Institute for Material and Beam Technology IWS in Dresden, together with partners from industry, has laid the groundwork for developing novel anti-PAK protective suits. The German Federal Ministry of Education and Research (BMBF) is funding the project with 1.24 million euros until December 2023 as part of the “Research for Civil Security” program.
 
The innovative protection concept of the new suits includes high-materials and intelligent monitoring: Modern nonwovens, as a central component of the protective suits, effectively prevent skin contact with the pollutants. Ultraviolet sensors are also integrated into the fabrics to determine when the textile protective shield is saturated with PAH and needs to be replaced. This provides double safety for rescue personnel. The new protective clothing has already passed the first tests in fire containers.

PAK-Accumulation over a Lifetime of Work Increases Cancer Risk
“On a single job, it may only be a few micrograms of PAH that get onto the skin through openings in the protective suit,” explains Felix Spranger, Group Manager Gas and Particle Filtration at Fraunhofer IWS. “The treacherous aspect of PAH is that they can continue to accumulate in the firefighters' bodies over an entire working life. Studies from Germany and the U.S. have shown increased incidences of cancer in this occupational group. Therefore, it was important to find solutions incorporating new technological approaches such as smart textiles.” For this purpose, Fraunhofer IWS joined forces with four other partners in 2020 to form the project “3D-Funktionsvliesstoffe mit integrierter Gassensorik für die Schutzbekleidung von Einsatzkräften” (3D-PAKtex, Engl: “3D functional nonwovens with integrated gas sensor technology for the protective clothing of emergency personnel”). To protect firefighters from the harmful PAH in flue gases and soot swirls in burning houses in the future, the collaborative partners pursued a two-pronged concept: on the one hand, the focus was on the development of fleece-based new filters, and on the other hand, on a sensor concept to monitor their functionality.
 
Activated Carbon Fleeces Filter Ring Molecules from Flue Gas
Fraunhofer IWS first identified suitable porous activated carbons that bind PAH particularly well. Project partner Norafin fixed these adsorbents with special binders in nonwovens optimized for fire applications. Norafin's partner S-GARD integrated the new additional nonwovens into a demonstration suit. The manufacturer added small closure pockets at sleeve openings, waistbands, and other points, which can accommodate the new additional filters using press studs at those points where, in the worst case, smoke gases could still enter the suit despite all insulation. If smoke gas flows past these spots, the fleece binds the toxins.

In addition, project partner JLM Innovation equipped the new filter fleeces with specifically engineered monitoring sensors based on fluorescence spectroscopy. These mini-spectrometers emit ultraviolet light of a precisely defined wavelength. When these UV rays hit PAH, the ring molecules first absorb their energy and then send back other UV rays at a slightly different wavelength. The sensors measure the returned light: The more intense, the higher the PAH concentration in the fleece. An electronic control unit in the firefighter's breast pocket evaluates this data and sends it to a smartphone via Bluetooth. The development and implementation of the repective software was accomplished by ATS Elektronik. It enables the rescuers to see in real-time how their PAH filters are filling up and when they need to be replaced.

In laboratory tests, the new nonwoven activated carbon filters have significantly reduced the flue gas PAH load. This was followed by practical simulations in fire containers: Experienced testers donned the suit prototypes, and set fire to mattresses, then rubber tires and other test objects in a shielded container to try out the new protective clothing in different fire scenarios.

“We will thoroughly evaluate these findings and continue to monitor the market to make a well-founded decision on possible series production,” announced Jonas Kuschnir of S-GARD. The new protective approach against PAHs entails certain additional costs, but the project’s results were promising.
 
High Market Potential for Intelligent Textiles Expected
Whatever the outcome of this decision, “3D-PAKtex” has, in any case, led to a considerable gain in expertise for the collaborative partners. The topic will also continue to occupy Fraunhofer IWS. Felix Spranger: “We still see some approaches, for example, to further improve the new protection technology's sensors and interfaces. From feedback, we know that industry partners still perceive great potential in such smart textiles, even beyond protective firefighting clothing.”

This is also consistent with the findings of international observers. For example, analysts at the British market research company IDTechEx expect the market for electronically enhanced or “smart” textiles to grow to the equivalent of around 713 million euros by 2033. Annual growth rates averaging 3.8 percent are expected.

Project Partners “3D-PAKtex”

  • Fraunhofer IWS contributes its expertise in the selection of filter materials and analytics
  • Norafin Industries from Mildenau in the Ore Mountains produces technical textiles
  • Hubert Schmitz (“S-GARD”) from Heinsberg produces protective clothing for firefighters
  • JLM Innovation from Tübingen is dedicated to sensor technology in intelligent textiles
  • ATS Elektronik developed the required software in Wunstorf, Germany
© DePoly
02.08.2023

Closing the loop on PET recycling

Ecole Polytechnique Fédérale de Lausanne (EPFL) spin-off DePoly has developed a method for recycling polyethylene terephthalate (PET) at ambient temperature, even when it’s dirty or mixed with other plastics. The firm confirmed the feasibility of its method with a pilot capable of processing 50 metric tons per year. Having recently raised CHF 12.3 million, DePoly is now building a pilot plant with 10 times that capacity.

Ecole Polytechnique Fédérale de Lausanne (EPFL) spin-off DePoly has developed a method for recycling polyethylene terephthalate (PET) at ambient temperature, even when it’s dirty or mixed with other plastics. The firm confirmed the feasibility of its method with a pilot capable of processing 50 metric tons per year. Having recently raised CHF 12.3 million, DePoly is now building a pilot plant with 10 times that capacity.

PET is a ubiquitous plastic used in everything from clothing and shoes to bottles and packaging. Because it’s recyclable, the material has earned solid green credentials. Switzerland produces 45,000 metric tons of PET bottles a year. Yet according to Swissrecycling, some 20% of these bottles aren’t recycled because they’re dirty or mixed with other plastics, so they end up being incinerated. However, the global PET recycling rate is less than 50%, according to a study, conducted for the environmental NGO Zero Waste Europe, so Switzerland is still a strong performer on this front.

In a bid to reduce the carbon footprint associated with PET, DePoly has developed a method for processing it at ambient temperature, even when it’s soiled or tightly interwoven with other fibers. The firm’s demonstrator has a capacity of 50 metric tons per year, and it now plans to use the CHF 12.3 million it raised a few days ago to build a pilot plant. This larger plant – scheduled to open in 2024 and capable of processing 500 metric tons a year – should prove that DePoly’s method is feasible at scale.
 
No need for sorting  
Samantha Anderson, originally from Canada and now DePoly’s CEO, moved to Switzerland in 2015 to begin her PhD at EPFL. When she first unveiled her PET recycling process, which she developed at EPFL’s Laboratory of Molecular Simulation (LMSO) in Sion, it seemed remarkably simple: plastics of all types and colors are mechanically ground then mixed with various chemical compounds – the exact recipe for which is a closely guarded secret. A few hours later, any non-PET plastics remain intact and can be separated out for further processing. The PET, meanwhile, is broken down into terephthalic acid (a powder) and ethylene glycol (a liquid), which can be used to make new material. The method slots seamlessly into existing recycling processes and could be adapted to other kinds of plastics. “Since there’s no heating involved, our method preserves the integrity of other materials like cotton, which is often mixed with PET in clothing and other items” says Anderson.

After graduating in 2019, Anderson decided she wanted to use her expertise to do “something useful for society.” Together with DePoly’s other founders – Bardiya Valizadeh and Christopher Ireland – she spent months testing different formulas for her process. The breakthrough moment came late one Friday when, for the first time, she saw the PET start to decompose before her eyes. By the time she returned to the lab on Monday morning, it had completely broken down. All that remained was for the team to refine the formula and adjust the dosages, hoping that their method would work for larger volumes of PET. Chemical processes can have a major drawback: the pollution they generate often outweighs any gains. “The substances we use are available over the counter, and they aren’t single-use,” says Anderson.

The DePoly team will now start building its first large-scale pilot plant in Valais. The facility will handle dirty and unsorted PET that can’t be recycled via the usual channels. The firm seems to be turning heads on the domestic startup scene: it won the prestigious >>venture>> Grand Prize in 2019 for its technology, and it’s been listed as one of the top 100 Swiss startups for the past three years in a row. But Anderson already has her sights set on the international market. Wouldn’t it be better to eliminate the issue at source by phasing out plastics from our lives? “I’m the first to admit that’s a better option,” she says. “But that’s still a long way off. In the meantime, we’re incinerating tons of PET every day just because it’s slightly soiled or hasn’t been properly sorted.”

More information:
PET Recycling chemical recycling
Source:

Cécilia Carron, Ecole Polytechnique Fédérale de Lausanne (EPFL)

(c) MycoWorks. Photos by Guillem Cruells, Set Design by Adriano Escribano
28.07.2023

MycoWorks: Reishi™ Committed for Commercial-Scale Production

July 20, biomaterials technology company MycoWorks announced three Reishi™ products and is unveiling performance breakthroughs in this revolutionary material made from Fine Mycelium™.

Founded in 2013, MycoWorks is marking its tenth anniversary this year with the launches of Reishi Doux, Reishi Natural, and Reishi Pebble. Each exceeds performance levels required by the luxury industry and behave similarly to that of some animal leathers. These will soon be produced at the world’s first commercial-scale Fine Mycelium factory in Union, South Carolina.

July 20, biomaterials technology company MycoWorks announced three Reishi™ products and is unveiling performance breakthroughs in this revolutionary material made from Fine Mycelium™.

Founded in 2013, MycoWorks is marking its tenth anniversary this year with the launches of Reishi Doux, Reishi Natural, and Reishi Pebble. Each exceeds performance levels required by the luxury industry and behave similarly to that of some animal leathers. These will soon be produced at the world’s first commercial-scale Fine Mycelium factory in Union, South Carolina.

Unparalleled Quality
“This is a breakthrough for the luxury industry,” said Thibault Schockert, CEO of luxury leather goods factory Cuir du Vaudreuil. “This improvement gives us the opportunity to introduce an entirely new category to our business,” referring to the latest Reishi™ material produced by MycoWorks that incorporates new breakthroughs in both Fine Mycelium fermentation and in mycelium tanning.
 
These milestones are the culmination of three decades of pioneering mycelium materials, beginning in the 1990s with the world’s first demonstrations of mycelium’s structural capabilities by MycoWorks co-founder Phil Ross. Prototypes of MycoWorks’ Fine Mycelium™ leather-like material were first unveiled in 2016, featuring both durability and softness but relatively low tensile strength. After achieving luxury-level performance over years of improvements, recent breakthroughs bring Reishi™ to yet another level of sensual and technical performance. Data on Reishi™ including softness, durability, flexibility, finish adhesion, tear strength, abrasion resistance, homogeneity and more are shown below, with additional data available upon request.
 
“Heritage-level quality can only be achieved with long-term dedication to discovery, paired with a commitment to craft and the transmission of deep expertise,” observed MycoWorks board member and former CEO of Hermès, Patrick Thomas. “MycoWorks’ Fine Mycelium™ platform is built on these principles, bringing together artisanal mastery with a rigorous approach to material innovation in a scalable way.”

Fine Mycelium™ as a biomaterial, not merely an ingredient
“The strength of our unique Fine Mycelium™ platform is evidenced by the new levels of performance we have achieved in the first half of this year in partnership with our European tannery partners,” said Bill Morris, MycoWorks VP of Product Management, “and our current product has surprised and delighted our brand partners, who have witnessed its evolution. Our latest material not only has Fine Mycelium™’s signature natural feel, but adds to it new levels of technical performance.”

MycoWorks’ brand partners include Hermès, General Motors, Ligne Roset, Heron Preston, Nick Fouquet, and others yet to be announced.

With these new Reishi™ articles, MycoWorks and its brand partners are excited to enter commercialization cycles—with some, such as Nick Fouquet and others, new styles and products Made With Reishi™.

MycoWorks’ Fine Mycelium™ platform is powerful in its tunability, and as a true, grown biomaterial sheet—rather than an added mycelium ingredient as found in other “mushroom leather”. MycoWorks’ process is unique in its ability to endlessly enable improvement. The recent quality advances were achieved by utilizing a combination of enhanced growth conditions plus a fundamentally new, patent-pending tanning approach that MycoWorks developed in-house. Because of the uniqueness of the Fine Mycelium process, every advance marks a  differentiator between MycoWorks’ technology platform and that of other biomaterial companies.

“While most plant- or mycelium-based alternative materials use plastic to meet baseline performance standards, MycoWorks has spent ten years taking no shortcuts, in order to achieve the biotech innovations behind our proprietary process,” says Matt Scullin, MycoWorks CEO. “Operating vertically—owning our entire technology stack, rather than licensing and outsourcing—has given us the depth of expertise required to bring a new material to market.”

Meeting luxury’s standards for material performance without the use of plastics means Fine Mycelium™ stands out in a field of alternatives that depend on polyurethane (PU) or polyvinyl chloride (PVC) films, fillers, or backings to provide strength and durability.

Source:

MycoWorks

05.06.2023

Sweater-Wrapped Robots Can Feel and React to Human Touch

The same qualities that make a knitted sweater comfortable and easy to wear might allow robots to better interact with humans.

RobotSweater, developed by a research team from Carnegie Mellon University's Robotics Institute, is a machine-knitted textile "skin" that can sense contact and pressure.
 
"We can use that to make the robot smarter during its interaction with humans," said Changliu Liu, an assistant professor of robotics in the School of Computer Science.

Just as knitters can take any kind of yarn and turn it into a sock, hat, or sweater of any size or shape, the knitted RobotSweater fabric can be customized to fit uneven three-dimensional surfaces.

The same qualities that make a knitted sweater comfortable and easy to wear might allow robots to better interact with humans.

RobotSweater, developed by a research team from Carnegie Mellon University's Robotics Institute, is a machine-knitted textile "skin" that can sense contact and pressure.
 
"We can use that to make the robot smarter during its interaction with humans," said Changliu Liu, an assistant professor of robotics in the School of Computer Science.

Just as knitters can take any kind of yarn and turn it into a sock, hat, or sweater of any size or shape, the knitted RobotSweater fabric can be customized to fit uneven three-dimensional surfaces.

"Knitting machines can pattern yarn into shapes that are nonflat, that can be curved or lumpy," said James McCann, an SCS assistant professor whose research has focused on textile fabrication in recent years. "That made us think maybe we could make sensors that fit over curved or lumpy robots."

Once knitted, the fabric can be used to help the robot "feel" when a human touches it, particularly in an industrial setting where safety is paramount. Current solutions for detecting human-robot interaction in industry look like shields and use very rigid materials that Liu notes can't cover the robot's entire body because some parts need to deform.

"With RobotSweater, the robot's whole body can be covered, so it can detect any possible collisions," said Liu, whose research focuses on industrial applications of robotics.
RobotSweater's knitted fabric consists of two layers of yarn made with metallic fibers to conduct electricity. Sandwiched between the two is a netlike, lace-patterned layer. When pressure is applied to the fabric — say, from someone touching it — the conductive yarn closes a circuit and is read by the sensors.

"The force pushes together the rows and columns to close the connection," said Wenzhen Yuan, an SCS assistant professor and director of the RoboTouch lab. "If there's a force through the conductive stripes, the layers would contact each other through the holes."

Apart from the design of the knitted layers — the culmination of dozens if not hundreds of samples and tests — the team faced another challenge in connecting the wiring and electronics components to the soft textile.

"There was a lot of fiddly physical prototyping and adjustment," McCann said. "The students working on this managed to go from something that seemed promising to something that actually worked."

What worked: wrapping the wires around snaps attached to the ends of each stripe in the knitted fabric.
Snaps are a cost-effective and efficient solution, such that even hobbyists creating textiles with electronic elements, known as e-textiles, could use them, McCann said.

"You need a way of attaching these things together that is strong, so it can deal with stretching, but isn't going to destroy the yarn," he said, adding that the team also discussed using flexible circuit boards.

Once fitted to the robot's body, RobotSweater can sense the distribution, shape and force of the contact. It's also more accurate and effective than the visual sensors most robots rely on now.

"The robot will move in the way that the human pushes it, or can respond to human social gestures," Yuan said.

In their research, the team demonstrated that pushing on a companion robot outfitted in RobotSweater told it which way to move or what direction to turn its head. When used on a robot arm, RobotSweater allowed a push from a person's hand to guide the arm's movement, while grabbing the arm told it to open or close its gripper.

In future research, the team wants to explore how to program reactions from the swipe or pinching motions used on a touchscreen.

The team — including SCS graduate students Zilin Si and Tianhong Catherine Yu, and visiting undergraduate student Katrene Morozov from the University of California, Santa Barbara — will present the RobotSweater research paper at the 2023 IEEE International Conference on Robotics and Automation (ICRA).

Begun by the three faculty members in a conversation over lunch one day, the collaboration among the team of researchers helped the RobotSweater come to life, McCann said.

"We had a person thinking about fabrication, a person thinking about the robotics integration, a person thinking about sensing, and a person thinking about planning and control," he said. "It's really nice to have this project where we have the full stack of people to cover each concern."

This research is supported by the CMU Manufacturing Futures Institute, made possible by the Richard King Mellon Foundation. The National Science Foundation provided additional funding.

More information:
robotic Interface knitting
Source:

Carnegie Mellon University